Is he doing precalculus with AoPS? If so, you might want to look into the AMC 10. Intro counting probability + intro number theory (+ intermediate counting and probability) are more than enough for a class; he could probably cover AP statistics in a comparatively short period of time if you wanted to add that (if you ask Daijobu nicely I'm sure she'll be happy to share her AP statistics material).
For science, if he's taking calculus next year, he could also take calc-based physics using a book like Halliday, Resnick, Krane. For chemistry, Clover Valley Chemistry offers live and self paced advanced honors chemistry classes.