Making something a priority means putting it ahead of other things. It took me like 30 years to learn that. I always thought making something a priority meant "Get all emotional about it and beat yourself up inside when it doesn't work out".
So if you really want to be organized, you've got to do it first. That means accepting that there will be less of something else going on. You've got to accept covering less material in a day or something. "Organize time" has to be like "math time" or "reading time", something that happens virtually every day. You wouldn't expect to add a foreign language without scheduling time for it, so don't expect to add organization without the same thing.
I teach public school, and one of my big challenges is getting papers back to kids. I am a pretty quick grader, but the handing back seems like such a waste of time. However, 85% of them won't pick up their own papers--and those are the ones that need immediate feedback. For ten years, I told myself every year "This year I will be better" but it never happened because I didn't define "better" as anything but "will feel guilty when I don't". This year I sat down and really thought about it: what would help my kids more: timely feedback or an extra 10 minutes of instruction a week? And I decided that they really needed the feedback, even though there is a real cost in total instructional time. So this year I have really prioritized handing back papers, but it's the absolute truth, there are things I'd like to teach that I am not getting to. I think it's worth it: more kids are doing their work, and doing it better, but it is a tradeoff. I regret the instructional time I've lost.
So I think you have to decide if being organized is worth anything, really, beyond a feeling that you "should be". Will it add to your children's education? What will it add? What are you doing now that you could give up to make the time to do it? I have no idea what the answer is to that question: I'm really, really early in my own homeschooling process. But I know these things work better when they are an informed choice, not just an emotional reaction.