My mom always wanted to homeschool and I think she would have done a wonderful job. My dad was VERY against it (funny enough, he is now my biggest supporter!) and so she didn't. However, if he would have been on board, I think we would have had a great education.
As it was, they still took us on educational vacations, we read ALL the time, and had a lot of exposure to awesome things. So even without homeschooling my parents definitely lit a fire for learning in me.